“Thelma & Louise” was the project that catapulted the “Wolfs” alum to stardom. The classic movie followed two best friends on the run and starred Davis, 69, as Thelma, and Sarandon, 78, as Louise. Pitt played untrustworthy thief J.D., whom Davis’ character fell for.

Brad Pitt has worked with some of Hollywood's biggest stars, like George Clooney, Leonardo DiCaprio and Morgan Freeman. And yet, even the Oscar-winning actor got starstruck by two major A-listers when he was just starting out in Hollywood.